Free release

(CARBOMETHOXYMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE

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Name: (CARBOMETHOXYMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
CAS: 1779-58-4
Synonyms: CMMTPPB ; (METHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE, 98+% ; PHOSPHONIUM, (2-METHOXY-2-OXOETHYL)TRIPHENYL-, BROMIDE ; (2-METHOXY-2-OXOETHYL)TRIPHENYLPHOSPHONIUM BROMIDE ; CARBMETHOXY METHYL TRIPHENYL PHOSPHONIUM BROMIDE ; METHOXYCARBONYLMETHYTLTRIPHENYLPHOSPHONIUMBROMIDE ; (CARBOMETHOXYMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE ; METHYL (TRIPHENYLPHOSPHONIO)ACETATE BROMIDE ; (METHOXYCARBONYLMETHYL)TRIPHENYLPHOSPHONIUM BROMIDE
MDL.: MFCD00011801
H bond acceptor: 2
H bond donor: 0
Smile: COC(=O)C[P+](c1ccccc1)(c2ccccc2)c3ccccc3.[Br-]
InChi: InChI=1S/C21H20O2P.BrH/c1-23-21(22)17-24(18-11-5-2-6-12-18,19-13-7-3-8-14-19)20-15-9-4-10-16-20;/h2-16H,17H2,1H3;1H/q+1;/p-1
InChiKey: InChIKey=VCWBQLMDSMSVRL-UHFFFAOYSA-M

Property

Melting Point: 165-170 DEG C (DEC)(LIT)
Comments: APPLICATION: REACTANT FOR SYNTHESIS OF: GSK-3 INHIBITORS USING THEWITTIG REACTION. SUBSTITUTED FURANONES FOR ANTIFUNGAL AND CYTOSTATIC ACTIVITIES. PHOTOCHROMIC DITHIENYLETHENE DERIVATIVES. GEM-DIIODOALKANES CONTAINING ALLYLIC ALCOHOLS. HIGHLY SUBSTITUTED CYCLOPENTENES AND BRAZILANES VIA AU-CATALYZED DEOXYGENATIVE NAZAROV CYCLIZATION. REACTANT FOR: ASYMMETRIC HYDROGENATION OF ALPHA,BETA-UNSATURATED ESTER-PHOSPHONATES. STUDIES OF THERMAL DECOMPOSITION OF PHOSPHONIUM ALKYL ESTER SALTS
NSC 136109
UNSPSC: 12352103
WGK: 3

Safety information

Symbol: GHS07 GHS07
Signal word: Warning
Hazard statements: H315-H319-H335
Precautionary statements: P261-P305 + P351 + P338
hazard symbol: Xi
Risk Code: R:36/37/38
Safe Code: S:26-36
WGK Germany: 3

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