2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE

Name：	2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE
CAS：	82495-75-8
Synonyms：	2-(TRIMETHYLSILYL)ETHOXYMETHYLTRIPHENYLPHOSPHONIUM CHLORIDE ; (TRIMETHYLSILYL)ETHOXYMETHYL TRIPHENYLPHOSPHONIUM CHLORIDE ; SEM-TRIPHENYLPHOSPHONIUM CHLORIDE
MDL.：	MFCD00043159
H bond acceptor：	1
H bond donor：	0
Smile：	C[Si](C)(C)CCOC[P+](c1ccccc1)(c2ccccc2)c3ccccc3.[Cl-]
InChi：	InChI=1S/C24H30OPSi.ClH/c1-27(2,3)20-19-25-21-26(22-13-7-4-8-14-22,23-15-9-5-10-16-23)24-17-11-6-12-18-24;/h4-18H,19-21H2,1-3H3;1H/q+1;/p-1
InChiKey：	InChIKey=NEUMNYXEDIPGJD-UHFFFAOYSA-M
Property
Melting Point：	145-149 DEG C(LIT)
Comments：	APPLICATION: REACTANT FOR: ENANTIOSELECTIVE SYNTHESIS OF (-)-SARAIN A USING ASYMMETRIC MICHAEL ADDITION, CYCLIZATION, RING-CLOSING METATHESIS, INTRAMOLECULAR STILLE COUPLING, AND LATE-STATE INSTALLATION OF TERTIARY AMINE-ALDEHYDE PROXIMITY INTERACTION. PREPARATION OF ALIPHATIC AND ALICYCLIC ALDEHYDES BY HOMOLOGATION OF ALDEHYDES. WITTIG REACTIONS. PREPARATION OF OPTICALLY ACTIVE (1S,5R)-(+)-3-AZABICYCLO[3.2.2]NON-6-EN-2-ONE VIA ENANTIOSELECTIVE INTRAMOLECULAR CYCLOPROPANATION UNSPSC: 12352103 WGK: 3
Safety information
Symbol：	GHS07
Signal word：	Warning
Hazard statements：	H315-H319-H335
Precautionary statements：	P261-P305 + P351 + P338
hazard symbol：	Xi
Risk Code：	R:36/37/38
Safe Code：	S:26-36
WGK Germany：	3