| Name： | 2,6-BIS[(3AR,8AS)-(+)-8H-INDENO[1,2-D]OXAZOLIN-2-YL]PYRIDINE |
| CAS： | 357209-32-6 |
| Synonyms： | 2,6-BIS[(3AR,8AS)-(+)-8H-INDENO[1,2-D]OXAZOLIN-2-YL]PYRIDINE ; (3AR,3'AR,8AS,8'AS)-2,2'-(2,6-PYRIDINEDIYL)BIS3A,8A-DIHYDRO-8H-INDENO[1,2-D]OXAZOLE ; (3AR,8AS)-IN-PYBOX |
| MDL.： | MFCD09265074 |
| H bond acceptor： | 5 |
| H bond donor： | 0 |
| Smile： | c1ccc2c(c1)C[C@H]3[C@@H]2N=C(O3)c4cccc(n4)C5=N[C@@H]6c7ccccc7C[C@@H]6O5 |
| InChi： | InChI=1S/C25H19N3O2/c1-3-8-16-14(6-1)12-20-22(16)27-24(29-20)18-10-5-11-19(26-18)25-28-23-17-9-4-2-7-15(17)13-21(23)30-25/h1-11,20-23H,12-13H2/t20-,21-,22+,23+/m0/s1 |
| InChiKey： | InChIKey=BZSJUFJXCHHRHW-MYDTUXCISA-N |
Property |
|
| Melting Point： | 284 DEG C (DEC) |
| Comments： | APPLICATION: CATALYTIC LIGAND USED FOR: [3+2] CYCLOADDITION OF N-TOSYL AZIRIDINES WITH ELECTRON-RICH ALKENES VIA SELECTIVE CARBON-CARBON BOND CLEAVAGE. ENANTIOSELECTIVE MUKAIYAMA-ALDOL REACTIONS. ENANTIOSELECTIVE CARBONYL-ENE REACTIONS. CU(I)-CATALYZED ASYMMETRIC ALKYNYLATION OF IMINO ESTERS WITH TERMINAL ALKYNES. ASYMMETRIC THREE-COMPONENT COUPLING REACTIONS CATALYZED BY A CU/PYBOX COMPLEX. ENANTIOSELECTIVE DIELS-ALDER REACTION. NI-CATALYZED CROSS-COUPLING REACTIONS OPTICAL ACTIVITY: [ALPHA]20/D +386 DEG, C = 1 IN METHYLENE CHLORIDE(LIT) UNSPSC: 12352100 WGK: 3 |
Safety information |
|
| Hazard statements： | H413 |
| WGK Germany： | 3 |
2,6-BIS[(3AR,8AS)-(+)-8H-INDENO[1,2-D]OXAZOLIN-2-YL]PYRIDINE
TradePlatform@qq.com
| Supplier | ||
|---|---|---|
| Custom | info@chems.com.cn | +86 (0)187 533 888 68 |