| Name： | (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) |
| CAS： | 205495-66-5 |
| Synonyms： | (S,S)-DACH-NAPHTHYL TROST LIGAND ; ROST LIGAND (NAPHTHYL) ; (1S,2S)-(-)-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPTHOYL)-1,2-DIAMINOCYCLOHEXANE ; (1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL) |
| MDL.： | MFCD02684552 |
| H bond acceptor： | 4 |
| H bond donor： | 2 |
| Smile： | c1ccc(cc1)P(c2ccccc2)c3ccc4ccccc4c3C(=O)N[C@H]5CCCC[C@@H]5NC(=O)c6c7ccccc7ccc6P(c8ccccc8)c9ccccc9 |
| InChi： | InChI=1S/C52H44N2O2P2/c55-51(49-43-29-15-13-19-37(43)33-35-47(49)57(39-21-5-1-6-22-39)40-23-7-2-8-24-40)53-45-31-17-18-32-46(45)54-52(56)50-44-30-16-14-20-38(44)34-36-48(50)58(41-25-9-3-10-26-41)42-27-11-4-12-28-42/h1-16,19-30,33-36,45-46H,17-18,31-32H2,(H,53,55)(H,54,56)/t45-,46-/m0/s1 |
| InChiKey： | InChIKey=VXFKMKXTPXVEMU-ZYBCLOSLSA-N |
Property |
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| Melting Point： | 232-237 DEG C/232-237°C/232-237°C |
| Comments： | APPLICATION: ASYMMETRIC ALLYLIC ALKYLATION LIGAND APPLICATION: TROST LIGANDS FOR ASYMMETRIC ALLYLIC ALKYLATION LEGAL INFORMATION: SOLD IN COLLABORATION WITH DR. REDDY'S LABORATORIES FOR RESEARCH PURPOSES ONLY. US PATENT 5739396 APPLIES OPTICAL ACTIVITY: [ALPHA]20/D -66.0 DEG, C = 1 IN METHANOL UNSPSC: 12352103 |
Safety information |
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| WGK Germany： | 3 |
(1S,2S)-(-)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2-DIPHENYLPHOSPHINO-1-NAPHTHOYL)
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